Showing posts with label sapphire crystal. Show all posts
Showing posts with label sapphire crystal. Show all posts

Monday, December 2, 2013

Sapphire Crystal Growth Method Used

1.Czochralski crystal pulling method ( referred to as CZ method ) :The raw
sapphire crystal
sapphire crystal
material is melted into molten metal is heated to the melting point , and then use molten metal contacting surface of the single sapphire crystal on the seed crystal and the molten metal due to the temperature difference between the solid-liquid interface cold forming , so the molten metal starts to solidify and the growth surface of the seed crystal and a single crystal seed crystal , the same crystal structure of the seed crystal while pulled up at a slow speed , and to a certain rotational speed , gradually solidified molten metal in the grain the kind of liquid-solid interface , forming an axis of symmetry of the single crystal ingot .

2.Kjeldahl crystal growth method ( referred KY method ): Similar to the original CZ method , the raw material is heated to the melting point melted into molten metal , then the seed of a single crystal surface exposed to molten metal in seed soup with melted solid-liquid interface and begin to grow a single crystal seed crystal having the same crystal structure , the seed crystal pulled up at a slow rate , but the formation of the seed crystal is pulled up the neck , the solidification rate of molten metal of such seed stable interface after the seed that is not pulled , do not rotate , so that only a single crystal controlled cooling rate down gradually solidified from above freezing for the entire single crystal ingot.

Sapphire Substrate Subdivision

1.C-Plane sapphire substrate:The most widely used, mainly for sapphire crystal
sapphire crystal
sapphire crystal

growth along the C axis mature technology, low cost, stable physical and chemical properties, so the C plane carried epitaxy technology is more mature and stable.

2.R-Plane or M-Plane of the sapphire substrate:Mainly used for growing nonpolar/semipolar GaN epitaxial film surface, in order to improve the luminous efficiency. Usually the sapphire substrate, an epitaxial film is grown along the C-axis, C-axis polar axis of GaN, GaN will occur in the quantum well active layer, a strong built-in electric field, resulting in lower emission efficiency, a nonpolar plane GaN epitaxial film may overcome this problem.

3.Patterned sapphire substrate (referred to as PSS):To grow or etching on the sapphire substrate designed to produce nano-scale microstructure pattern specific rules in order to control the output of the LED light in the form, and can also reduce the growth on sapphire substrates dislocations between GaN and improve the epitaxial quality and enhance the quality of LED internal efficiency, increase the light extraction efficiency.

Thursday, November 14, 2013

Sapphire Substrate In Microelectronics Substrate

sapphire substrate body
sapphire substrate body
GaN Epitaxial Semiconductor Substrate Body

Conventional silicon and gallium arsenide semiconductor materials were first-generation and second -generation representatives to promote the development of their microelectronics, photonics technology development , as a basis of the information technology has brought tremendous change people's lives.However, the performance limitations of the material itself , the first and second generations of semiconductor material can only work in an environment below 200 ℃ , and anti-radiation, high voltage breakdown performance and so can not meet the development of modern electronic technology for high-temperature , high-power , high-frequency , high-pressure and anti-radiation, capable of emitting blue new requirements. In this case , the choice of materials, new electronic devices launched the third generation of semiconductors, GaN and SiC wide bandgap semiconductor materials become the representative of the third generation.In the third -generation semiconductors,GaN materials, more and more people 's attention. GaN has many advantages: the band gap , high electron saturation velocity , good thermal conductivity, high breakdown electric field , low dielectric constant , good thermal stability , chemical stability . Thus, the third -generation semiconductor material properties will eventually cause them to be in the aerospace, exploration , nuclear energy development , satellite, communications, automotive engines, displays, new light source , laser printing, memory, and other fields have broad application prospects . As early as the 1970s, people began to explore the GaN growth process , but due to technical limitations material growth can not get high-quality GaN crystal. With the growth of technology development , has appeared in molecular beam epitaxy (MBE) and chemical vapor deposition (CVD) and other new methods, which greatly promoted the research on GaN . Sapphire crystal as a substrate material, the GaN crystal has the same structure, with a high temperature chemical stability , thermal properties, and is easy to obtain large size and relatively cheap, etc. , although there is a big GaN lattice mismatch . With the growth of technology continues to improve , has been able to produce a quality epitaxy on sapphire
GaN crystal,( 0001 ) plane of the sapphire wafer has a practical application of the most desirable substrate material .

SOS Microelectronic Circuits

SOS (Silicon on Sapphire) microelectronic circuits , refers to the sapphire wafer ( 1-102 ) plane of a layer of a silicon single crystal grown by heteroepitaxial film , and then the silicon single crystal film technology for fabricating a semiconductor device . SOS microelectronic circuits due to having high speed, low power consumption and anti- radiation,etc.,so the watch type mobile phone , desktop or laptop computers, high-speed, high-frequency radio communications, small satellites , spacecraft , and the development of the space shuttle have a particularly important application . Sapphire and silicon have similar thermal expansion coefficient. In the ( 1-102 ) plane of the sapphire wafer and, using hetero-epitaxially grown layer method
( 100 ) plane of the silicon single crystal film , and then the silicon single crystal film fabricating a semiconductor device . Sapphire crystal structural integrity of the substrate is to guarantee access to the structural integrity of the main conditions for silicon single crystal film .

ZnO,InN,And Other Epitaxial Film Substrate Body

Temperature band gap of ZnO 3.37eV, corresponding to ultraviolet light for direct bandgap wurtzite structure Ⅱ - Ⅵ semiconductor crystals with similar semiconductor GaN, ZnS , compared , ZnO has higher exciton binding energy , and its value of 60meV, can greatly reduce the low temperature lasing threshold. Thus ZnO at room temperature or higher temperatures are expected to achieve the exciton gain, thus the low threshold to obtain short-wavelength lasers applications . Since the implementation of ZnO UV optically pumped lasing at room temperature after.

The growth of ZnO single crystal thin film , p-type doping research worldwide attracted the attention of many research groups . Sapphire by low cost and high crystal ZnO has been widely used as a substrate epitaxial layer .
In Ⅲ - Ⅴ nitride in , InN is attracting more and more attention . And GaN, AlN , compared , InN Has the smallest effective mass , in theory, has the highest carrier mobility , so that it is in high-speed micro Electronic devices has a broad application prospects. While Ⅲ - Ⅴ nitride , it also has the smallest
Direct band gap , and its value is about 0.8eV , which makes Ⅲ - Ⅴ nitride AlN emission wavelength from the ultraviolet (6.2eV) extending into the infrared region of InN (0.8eV), a light emitting device prepared in a suitable materials . However, preparation of InN single crystal is very difficult , so far people InN research is still in the initial stage , in foreign countries , Masuoka and others with MOVPE method on sapphire substrates have been the first successful single-crystal InN epitaxial film . In China, Xiao Hongling , who use radio frequency plasma-assisted molecular beam epitaxy (RF-MBE) method on sapphire substrate obtained crystals of good quality single crystal InN epitaxial film . Superconducting thin films such as YBa2Cu3O7 - δ (YBCO) of the microwave surface resistance Rs than conventional metal materials several orders of magnitude , can be used to design high-performance passive microwave devices, such as filters , resonators , delay lines . Sapphire crystal dielectric constant , low dielectric loss , microwave performance, mechanical strength, and thermal conductivity is high , the substrate is LaAlO3.

More than 20 times . Large areas of industrial production of sapphire single crystal materials have been relatively inexpensive price , and therefore is a good substrate material . As the ferroelectric substrate material : used ferroelectric memory , spatial light modulators, optical switches, etc. ferroelectric random access memory , infrared detectors , drive, optical modulators, displays , etc., with excellent performance compelling and use value.

Sapphire crystal as a substrate material , the demand on the international market is getting bigger, while the crystal quality and size requirements are also rising .

Laser Host,Optics And Other Uses

Sapphire crystal is an excellent laser host material, such as titanium-doped
laser host,optics
laser host,optics
sapphire crystal isthe world's most excellent wideband tunable laser crystal recently, its tunable wavelength range of 660 ~ 1200nm. Moulton first reported in 1982 since the laser oscillation , because it has a wide tuning range and a high gain , etc., have been widely studied and adequate . Sapphire optical penetration with a very wide range , from the near ultraviolet light in the infrared wavelengths 0.9nm to 5.5μm have good light transmittance , and in the band of 0.25 ~ 4.5μm remain penetration of more than 80% rate ; making large size, high integrity sapphire single crystal has been used as the U.S. LICO (Laser interferometer gravitational observatory) engineering of large-scale gravity waves measuring cosmic interference means the preferred spectral element matrix material . Sapphire crystal in the civilian field of application has also been very extensive, for example, in medical equipment, environmental protection equipment , laser equipment, chemical equipment , high vacuum test equipment, textile industry, fiber guide wire panels , barcode scanners scan window , never worn type Rado watch Mongolia and so on.

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Wednesday, November 13, 2013

Sapphire Crystal Applications

The chemical composition of the sapphire crystal alumina (α-Al2O3), is composed
sapphire crystal
sapphire crystal
of three aluminum atoms and two oxygen atoms covalently type combination , the crystal structure of hexagonal crystal structure , as 2,3,4 shown . In terms of color , pure alumina is rendered transparent and colorless crystals , because of different color element ion penetration in the growing sapphire,thereby sapphire show different colors. When in nature when grown sapphire crystal containing titanium ions (Ti3 +) and iron ions (Fe3 +) , makes the crystal appear blue , and a blue sapphire (Blue Sapphire). When a crystal containing chromium ion (Cr3 +) , makes the crystal appear red, and a ruby (Ruby). And when the crystal containing nickel ions (Ni3 +) , the cause is yellow crystals , which become yellow sapphire . Table 1 lists the characteristics of sapphire table.Sapphire crystal chemically very stable, generally insoluble in water and from acid , alkali etching , only at higher temperatures (300 ℃) for the hydrofluoric acid , phosphoric acid and potassium hydroxide of melting erosion.

Sapphire crystal is very hard, as the Mohs hardness 9 , second only to the hardest diamond . It has good light transmission, thermal conductivity and electrical insulation, mechanical mechanical properties, and has the characteristics of abrasion and erosion . Sapphire crystal melting point of 2050 ℃, boiling point 3500 ℃, the maximum operating temperature up to 1900 ℃. Therefore, the sapphire crystal as an important technique that has been widely used in science and technology, defense and civilian industries in many areas .

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Molybdenum Crucible Furnace with Sapphire Crystal

molybdenum crucible
molybdenum crucible
Currently used sapphire crucible furnace iridium crucible ,crucible molybdenum crucible.From a practical point of view,iridium crucible minimal contamination of sapphire,but the price is too expensive,the cost is high ; while tungsten and molybdenum crucible crucible relatively cheaper,but contamination is relatively large.

Using iridium crucible generally iridium crucible itself is the heat generator, but using tungsten,molybdenum crucible is less used crucible itself do heat. Ikal-200 type crystal growth furnace,using molybdenum crucible,molybdenum heat shield,tungsten heating body,volatile at high temperatures molybdenum and tungsten atoms.Of course,tungsten,molybdenum crucible itself is not doing no heating element,is relative,process selection and temperature field settings are very critical factor.Different crystal growth method using the crucible will be different, such as the Kyropoulos (KY) Average of tungsten crucible , heat exchange method (HEM) generally used molybdenum crucible,because the heat exchange last to fall through to take a single crystal,and the molybdenum crucible cheapest price . According crucible manufacturing process, can be divided into pressed and sintered crucible and the crucible spinning,pressed and sintered crucible of lower quality,purity,low density,relatively short life,the price is relatively cheap;spinning crucible of higher quality, purity ,density higher , longer service life , high price.Domestic crystal growth furnace is generally used to suppress sintering crucible .

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